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Difference between caustic soda and soda ash

Caustic soda(cas1310-73-2) and soda ash are both common names for sodium hydroxide (NaOH) and sodium carbonate (Na2CO3), respectively. They are both bases, which means they have a high pH and can neutralize acids. They are also both widely used in various industrial applications, such as pulp and paper, water treatment, detergent and soap production, and pH adjustment. However, they have some important differences that affect their performance, cost, and handling.

Chemical properties

Caustic soda is a strong base that dissociates completely in water, producing hydroxide ions (OH-) and sodium ions (Na+). It has a pH of 14 in aqueous solution and can react with many organic and inorganic substances. It is highly corrosive and can cause severe burns on contact with skin or eyes.

Soda ash is a weak base that partially dissociates in water, producing carbonate ions (CO3 2-) and bicarbonate ions (HCO3 -) along with sodium ions (Na+). It has a pH of around 11 in aqueous solution and can react with some acids and metals. It is less corrosive than caustic soda but can still irritate skin or eyes.

Physical properties

Caustic soda(cas1310-73-2) is usually sold as flakes, pellets, or liquid solution. It is hygroscopic, which means it absorbs moisture from the air and can become lumpy or sticky. It also generates heat when dissolved in water, which can cause boiling or splashing hazards. It should be stored in a cool, dry, and well-ventilated place, away from acids, metals, and flammable materials.

Soda ash is usually sold as a white powder or granules. It is not hygroscopic but can cake or harden when exposed to moisture. It does not generate heat when dissolved in water but can form clumps or precipitates if the water is too hard or cold. It should be stored in a dry and sealed container, away from moisture, acids, and oxidizing agents.

Economic factors

Caustic soda(cas1310-73-2) is more expensive than soda ash per unit weight, but it is also more efficient in terms of alkalinity. One kilogram of caustic soda can provide the same amount of alkalinity as 1.33 kilograms of soda ash. However, the actual consumption rates may vary depending on the application and the reaction conditions. In some cases, caustic soda may require less dosage, less equipment, or less maintenance than soda ash, which can lower the overall operating costs.

Soda ash is cheaper than caustic soda per unit weight, but it is also less efficient in terms of alkalinity. One kilogram of soda ash can provide only 75% of the alkalinity of one kilogram of caustic soda. However, the actual consumption rates may depend on the application and the reaction conditions. In some cases, soda ash may offer advantages such as lower energy consumption, lower corrosion risk, or lower environmental impact than caustic soda, which can improve the overall profitability.

Here’s a quick comparison between caustic soda and soda ash:

PropertyCaustic Soda (Sodium Hydroxide)Soda Ash (Sodium Carbonate)
Chemical FormulaNaOHNa2CO3
Alkalinity LevelHighly alkalineAlkaline
Common UsesIndustrial cleaning, manufacturingGlass production, water treatment
Effects on MaterialsCorrosiveLess corrosive
Physical FormLiquid or solidGranular powder

How to Buy Sodium hydroxide?

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